1. "Oxygenated Species in the Products of Fluorination of [60]-Fullerene and [70]-Fullerene by Fluorine Gas."
    R. Taylor, G. J. Langley, J. H. Holloway, E. G. Hope, A. K. Brisdon, H. W. Kroto and D. R. M. Walton,
    J. Chem. Soc., Perkin Trans., 2, (1995), 181-187.
  2. "Cleavage of Both Alkyl C-H Bonds and Aryl C-F Bonds and Concomitant C-C Bond Formation in a Pentamethylcyclopentadienyl Rhodium Phosphine Complex: X-Ray Structure of [{h 5-C5Me3-1,3-(CH2C6F4P(C6F5)CH2)2}RhCl]+ [BF4]-."
    M. J. Atherton, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karacar, D. R. Russell and G. C. Saunders,
    J. Chem. Soc., Chem. Commun., (1995), 191-192.
  3. * "Reactions of Transition-Metal Carbonyls with Anhydrous HF."
    S. A. Brewer, J. H. Holloway and E. G. Hope,
    J. Fluorine Chem., (1995), 70, 167-169.
  4. * "Ruthenium and Osmium Acyl Fluoride Complexes. Crystal Structure of [
    OC-6-13][RuF2(CO)2(PPh3)2].CD2Cl2."
    S. A. Brewer, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope, D. R. Russell and P. G. Watson,
    J. Chem. Soc., Dalton Trans., (1995), 1073-1076.
  5. "Tris(2,6-difluorophenyl)phosphite Complexes of Platinum Group Metals. Structure of trans-[PtCl2(PEt3){P(O-2,6-C6H3F2)3}]."
    K. S. Coleman, J. H. Holloway, E. G. Hope, D. R. Russell, G. C. Saunders and M. J. Atherton,
    Polyhedron, (1995), 14, 2107-2113.
  6. * "A Platinum(II) Phosphine Complex Containing the OTeF5- Ligand."
    L. A. Buggey and E. G. Hope,
    J. Fluorine Chem., (1995), 73, 247-249.
  7. * "The Reactions of
    cis-[Os(CO)4(CH3)2] and
    cis-[Re(CO)4(PPh3)(CH3)] with Anhydrous HF and HOTeF5. Compatability of Phosphine, Alkyl and OTeF5- Ligands in Low-Valent Transition Metal Complexes."
    S. A. Brewer, L. A. Buggey, J. H. Holloway and E. G. Hope,
    J. Chem. Soc., Dalton Trans., (1995), 2941-2944.
  8. * "Synthesis and Characterisation of Iridium Carbonyl Fluorides."
    S. A. Brewer, A. K. Brisdon, J. H. Holloway, E. G. Hope, L. A. Peck and P. G. Watson,
    J. Chem. Soc., Dalton Trans., (1995), 2945-2948.
  9. "Fluorination."
    J. H. Holloway and E. G. Hope,
    Chapter 6 in The Chemistry of Fullerenes, Ed. R. Taylor, World Scientific, Singapore. (1995), 109-122.
  10. "Pentafluorophosphine Complexes of Rhodium: EXAFS Studies of [{Rh{PPhx(C6F5)3-x(µ-Cl}n] (x = 0-2) and [{Rh{(C6F5)2PCH2CH2P(C6F5)2](µ-Cl)}2]. Crystal Structures of [RhCl(PPh3){(C6F5)2PCH2CH2P(C6F5)2}].thf and (C6F5)2PCH2CH2P(C6F5)2."
    M. J. Atherton, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karacar, L. A. Peck and G. C. Saunders,
    J. Chem. Soc., Dalton Trans., (1995), 4029-4037.
  11. * "EXAFS Studies on Low-Valent Transition Metal Fluorides."
    K. S. Coleman, J. H. Holloway, E. G. Hope, L. A. Peck and A. K. Brisdon,
    Synchrotron Radiation Department Scientific Reports. Appendix to the Daresbury Annual Report, (1995), 380.
  12. * "EXAFS Studies on Bromine Oxide Fluorides."
    J. H. Holloway, E. G. Hope, L. Wootton and A. K. Brisdon,
    Synchrotron Radiation Department Scientific Reports. Appendix to the Daresbury Annual Report, (1995), 388.
  13. "Tris(pentafluorophenyl)phosphine Complexes of Iridium: Molecular Structure of trans-[IrBr(CO){P(C6F5)3}2]."
    J. H. Holloway, E. G. Hope, D. R. Russell, G. C. Saunders and M. J. Atherton,
    Polyhedron, (1996), 15, 173-175.
  14. * "Cyclopentadienyl Metal Teflate Complexes."
    M. C. Crossman, E. G. Hope and G. C. Saunders,
    J. Chem. Soc., Dalton Trans., (1996), 509-511.
  15. * "Selective Fluorination of Dichloromethane by Highest Oxidation State Transition Metal Oxide Fluorides."
    J. H. Holloway, E. G. Hope, P. J. Townson and R. L. Powell,
    J. Fluorine Chem., (1996), 76, 105-107.
  16. * "Pentafluorooxotellurate(VI) Acid as a Protic Acid."
    L. A. Buggey and E. G. Hope,
    J. Fluorine Chem., (1996), 76, 109-110.
  17. "Novel Synthesis Using Inorganic Fluorides."
    J. H. Holloway and E. G. Hope,
    J. Fluorine Chem., (1996), 76, 209-212.
  18. * "Crystal Structure of µ2-Hydridododecacarbonyltriosmium Dioxooctafluoro-µ2-fluoro- ditungsten."
    M. C. Crossman, J. Fawcett, E. G. Hope and D. R. Russell,
    J. Organomet. Chem., (1996), 514, 87-91.
  19. "C-F and C-H Bond Activation and C-C Bond Formation in h -Pentamethylcyclopentadienyl-Rhodium and Iridium Phosphine Complexes. Crystal Structures of [(h 5-C5Me5)MCl{(C6F5)2PCH2CH2P(C6F5)2}]+.BF4- (M = Rh, Ir)."
    M. J. Atherton, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karaçar, D. R. Russell and G. C. Saunders,
    J. Chem. Soc., Dalton Trans., (1996), 3215-3220.
  20. * "The Oxidative Fluorination of the Platinum Metals by Elemental Fluorine in Solution at Room Temperature."
    J. H. Holloway, E. G. Hope and C. D. Puxley,
    Eur. J. Solid-State Inorg. Chem., (1996), 33, 821-829.
  21. "Structure of cis-PtCl2(PEt3){P(OC6H3F2)3}."
    J. Fawcett, J. H. Holloway, E. G. Hope, G. C. Saunders and M. J. Atherton,
    Acta. Crystallogr. C, (1996), C52, 2463-2464.
  22. * "The Halogens and Noble Gases."
    E. G. Hope,
    Chapter 7 in Annual Reports of the RSC, Section A Inorganic Chemistry, ed. F J Berry and N G Connelly, RSC, Cambridge, (1996), 103-112.
  23. * "Pentafluorophenylphosphine Complexes of Rhodium(I)."
    K. S. Coleman, J. H. Holloway, E. G. Hope, L. A. Peck, G. C. Saunders and M. J. Atherton,
    Synchrotron Radiation Department Scientific Reports. Appendix to the Daresbury Annual Report, (1996), 83.
  24. * "Preparation and Characterisation of Dimolybdenum Complexes containing Fluorophenylimido Ligands."
    P. Bhattacharyya, J. Fawcett, J. H. Holloway, E. G. Hope and G. C. Saunders,
    J. Chem. Soc., Dalton Trans., (1997), 199-203.
  25. "Structure and Electronic Impact of Fluorine in the Ortho Positions of The Phenoxy Groups of Phenyl-Phosphite and -Phosphinite Ligands in Compounds of Platinum Group Metals."
    M. J. Atherton, J. Fawcett, A. P. Hill, J. H. Holloway, E. G. Hope, D. R. Russell, G. C. Saunders and R. M. J. Stead,
    J. Chem. Soc., Dalton Trans., (1997), 1137-1147.
  26. * "Synthesis and Characterisation of Ruthenium Carbonyl Fluorides."

    27. K. S. Coleman, J. H. Holloway and E. G. Hope,
    J. Chem. Soc., Dalton Trans., (1997), 1713-1717.
  27. * "Fluorous Phase Soluble Rhodium Complexes: X-ray Structure of [RhCl(CO)(P(C2H4C6F13)3)2]."
    J. Fawcett, E. G. Hope, R. D. W. Kemmitt, D. R. Paige, D. R. Russell, A. M. Stuart, D. J. Cole-Hamilton and M. J. Payne,
    J. Chem. Soc., Chem. Commun., (1997), 1127-1128.
  28. "Halogen and Interhalogen Reactions with [60]Fullerene: Preparation and Characterisation of C60Cl24 and C60Cl18F14."

    29. A. J. Adamson, J. H. Holloway, E. G. Hope and R. Taylor,
    Fullerene Science and Technology, (1997), 5, 629-642.
  29. "Pentafluorophenylphosphine Complexes of Platinum(II). Structure of trans-[PtCl2(PEt3){PPh2(C6F5)}]."
    J. Fawcett, J. H. Holloway, E. G. Hope, D. R. Russell, G. C. Saunders and M. J. Atherton,
    J. Chem. Soc., Dalton Trans., (1997), 2217-2220.
  30. * "Air-Stable Ruthenium(II) and Osmium(II) Fluoride Complexes. X-ray Crystal Structures of [
    OC-6-13][MF2(CO)2(PR3)2] (M = Ru, PR3 = PEtPh2; M = Os, PR3 = PPh3, Pcy3)."
    K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope and D. R. Russell,
    J. Chem. Soc., Dalton Trans., (1997), 3557-3562.
  31. "UV-Visible Spectroscopic Studies of Group 8-10 Transition Metal Trifluorides."
    A. L. Hector, W. Levason, M. T. Weller and E. G. Hope,
    J. Fluorine Chem., (1997), 84, 161-165.
  32. * "The Halogens and Noble Gases."
    E. G. Hope,
    Chapter 7 in Annual Reports of the RSC, Section A Inorganic Chemistry, ed. F J Berry and N G Connelly, RSC, Cambridge, (1997), 105-116.
  33. * "Reaction of Ruthenium(II) and Osmium(II) Hydrides with Anhydrous HF."

    34. K. S. Coleman, J. H. Holloway, E. G. Hope and J. Langer,
    J. Chem. Soc., Dalton Trans., (1997), 4555-4559.
  34. * "Phosphorus(III) Ligands with Fluorous Ponytails."
    P. Bhattacharya, D. Gudmunsen, E. G. Hope, R. D. W. Kemmitt, D. R. Paige and A. M. Stuart,
    J. Chem. Soc., Perkin Trans., 1, (1997), 3609-3612.
  35. "UV-Visible Spectroscopic Studies of Fluorides and Fluoroanions of Silver(III) and Gold(III) and (V)."
    A. L. Hector, W. Levason, M. T. Weller and E. G. Hope
    J. Fluorine Chem., (1997), 86, 105-108.
  36. * "Fluoride as a Ligand in Coordination Compounds. Solution Decomposition of Platinum (II) Fluoride Cations; Crystal Structure of [Pt(PPh3)2(C6H4PPh2)][SbF6].CD2Cl2."
    H. C. S. Clark, J. Fawcett, J. H. Holloway, E. G. Hope, L. A. Peck and D. R. Russell,
    J. Chem. Soc., Dalton Trans., (1998), 1249-1252.
  37. "Activation of C-F bond and C-H bonds in polyalkylcyclopentadienylrhodium complexes: crystal structure of [(h 5-C5Me4Et)RhCl{(C6F5)2PCH2CH2P(C6F5)2}]+.BF4-."
    M. J. Atherton, J. Fawcett, J. H. Holloway, E. G. Hope, S. M. Martin, D. R. Russell and G. C. Saunders,
    J. Organomet. Chem., (1998), 555, 67-79.
  38. "Mild Fluorination of Oxo-anions; a Clean Route to Group 6 and 7 Transition Metal Oxide Fluorides."
    A. K. Brisdon, J. H. Holloway and E. G. Hope,
    J. Fluorine Chem., (1998), 89, 35-37.
  39. "Self-assembly of a chiral-at-metal rhodium complex cation via regioselective carbon-fluorine and -hydrogen bond activation and carbon-carbon formation."
    M. J. Atherton, J. H. Holloway, E. G. Hope and G. C. Saunders,
    J. Organomet. Chem., (1998), 558, 209-211.
  40. "Carbon-fluorine Bond Activation in the Reactions between 1,2-Bis{bis(2,6-difluorophenyl)phosphino}ethane and [{MCl(µ-Cl)(h -C5Me5)}2] (M = Rh or Ir)."
    J. Fawcett, S. Friedrichs, J. H. Holloway, E. G. Hope, V. McKee, M. Nieuweenhuyzen and G. C. Saunders,
    J. Chem. Soc., Dalton Trans., (1998), 1477-1484.
  41. * "Reactions of [M2(CO)10] (M = Mn, Re) with Xenon bispentafluorooxo-tellurate(VI) and -selenate(VI)."
    M. C. Crossman, E. G. Hope and L. J. Wootton,
    J. Chem. Soc., Dalton Trans., (1998), 12.
  42. * "The Halogens and Noble Gases."
    E. G. Hope, Chapter 7 in Annual Reports of the RSC, Section A Inorganic Chemistry, ed. F J Berry and N G Connelly, RSC, Cambridge, (1998), 125-136.
  43. "Isolation of oxides and hydroxides derived from fluoro[60]fullerenes."
    O. V. Boltalina, J. H. Holloway, E. G. Hope, J. M. Street and R. Taylor,
    J. Chem. Soc., Perkin Trans., 2, (1998), 1845-1850.
  44. * "Reactions of iridium and rhodium hydrides with anhydrous HF; crystal structure of [Rh(CO)(PPh3)3][BF4].thf."
    H. C. S. Clark, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope, J. Langer and I. M. Smith,
    J. Fluorine Chem., (1998), 91, 207-211.
  45. * "Platinum Group Metal Complexes of Fluorous Derivatised Aryl Phosphine Ligands."
    J. Fawcett, E. G. Hope, R. D. W. Kemmitt, D. R. Paige, D. R. Russell and A. M. Stuart,
    J. Chem. Soc., Dalton Trans., (1998), 3751-3764.
  46. * "Platinum Group Metal Complexes of the Fluorous Derivatised Analogue of Bis(Diphenylphosphino)ethane."
    E. G. Hope, R. D. W. Kemmitt and A. M. Stuart,
    J. Chem. Soc., Dalton Trans., (1998), 3765-3770.
  47. "Electrochemical Investigations in Liquid and Supercritical 1,1,1,2-Tetrafluoroethane (HFC 134a) and Difluoromethane (HFC 32)."
    A. P. Abbott, C. A. Eardley, J. C. Harper and E. G. Hope,
    J. Electroanal. Chem., (1998), 457, 1-4.
  48. "Distortion in Rhombohedral Trifluorides and the Mixed Valence Structure of "R-NiF3"."
    A. L. Hector, E. G. Hope, W. Levason and M. T. Weller,
    Z. Anorg. Allg. Chem., (1998), 624, 1982-1988.
  49. "trans-(Pentafluorophenyl-C)carbonylbis[(pentafluorophenyl)diphenylphosphine-P]iridium(I)"
    J. Fawcett, E. G. Hope and L. A. Peck,
    Acta Cryst., Section C, (1998), C54, 1752-1753.
  50. "Recent Advances in Noble-Gas Chemistry."
    J. H. Holloway and E. G. Hope,
    Adv. Inorg. Chem., (1999), 46, 51-100.
  51. "A Convenient Access to Triarylphosphines with Fluorous Phase Affinity."
    D. Sinuo, G. Pozzi, E. G. Hope and A. M. Stuart,
    Tetrahedron Letts., (1999), 40, 849-852.
  52. "The Molecular Structure of Vanadyl Nitrate, VO(NO3)3, in the Gas Phase by Electron Diffraction and Ab Initio Calculations."
    B. A. Smart, H. E. Robertson, D. W. H. Rankin, E. G. Hope and C. J. Marsden,
    J. Chem. Soc., Dalton Trans., (1999), 473-477.
  53. "Hydroformylation of Higher Olefins in Supercritical CO2."
    A. Banet, I. Chadbond, B. T. Heaton, E. G. Hope, J. A. Iggo, R. D. W. Kemmitt, D. R. Paige, A. M. Stuart, R. Whyman and J. Xiao,
    in Proceedings of the 6th Meeting on Supercritical Fluids: Chemistry and Materials, Nottingham, UK, (1999), pp. 305-308.
  54. * "Synthesis and Characterisation of [
    OC-6-33][OsCl2(CO)2L2] (L = phosphine). Crystal structure of [
    OC-6-33][OsCl2(CO)2(PEt3)2]."
    H. C. S. Clark, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope, J. Redding and D. R. Russell,
    Polyhedron, (1999), 18, 1207-1210.
  55. "Intermediates and Anion Effects in the Carbon-Fluorine and -Hydrogen Bond Activating/Carbon-Carbon Bond Forming Reactions of h 5-pentamethylcyclopentadienyl-rhodium halide complexes; Crystal structure of [{h 5-C5Me3[CH2C6F4P(C6F5)CH2]2-1,3}RhBr]+Br-."
    M. J. Atherton, J. Fawcett, J. H. Holloway, E. G. Hope, D. R. Russell and G. C. Saunders,
    J. Organomet. Chem., accepted (November, 1998).
  56. * "Chemistry in Perfluorinated Organic Solvents."
    E. G. Hope and A. M. Stuart,
    Chapter 14 in Advanced Inorganic Fluorides: Synthesis, Characterisation and Applications, ed. T. Nakajima, A. Tressauc and B. Zemva, (1999), in press.
  57. * "The Halogens and Noble Gases."
    E. G. Hope,
    Chapter 7 in Annual Reports of the RSC, Section A Inorganic Chemistry, ed. F J Berry and N G Connelly, RSC, Cambridge, in press.
  58. "Highly active, selective and recyclable catalysts for the Hydroformylation of Long-Chain Alkenes under Fluorous Biphasic Conditions."
    D. Gudmunsen, A. M. Stuart, E. G. Hope, G. P. Schwarz, D. F. Foster and D. J. Cole-Hamilton,
    in preparation.
  59. * "Synthesis and Coordination Chemistry of
    meta-Perfluoroalkyl-Derivatised Triarylphosphines."
    E. G. Hope, R. D. W. Kemmitt, D. R. Paige, A. M. Stuart and D. R. W. Wood,
    Polyhedron, accepted (June 1999).
  60. * "Fluorous Biphase Catalysis."
    E. G. Hope and A. M. Stuart,
    J. Fluorine Chem., accepted (August 1999).
  61. * "Phosphorus(III) Ligands in Fluorous Biphase Catalysis."
    P. Bhattacharyya, B. Croxtall, J. Fawcett, J. Fawcett, D. Gudmunsen, E. G. Hope, R. D. W. Kemmitt, D. R. Paige, D. R. Russell, A. M. Stuart and D. R. W. Wood,
    J. Fluorine Chem., submitted.
  62. * "The Rhodium Catalysed Hydrogenation of Styrene in the Fluorous Biphase."
    E. G. Hope, R. D. W. Kemmitt, D. R. Paige and A. M. Stuart,
    J. Fluorine Chem., accepted (July 1999).

* Principle author on publication.

Last updated: 13 April 2000 17:06
Dr E.G. Hope

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