1. Oxygenated Species in the Products of Fluorination of [60]- and [70]-Fullerene by Fluorine Gas.
    R. Taylor, G.J. Langley, J.H. Holloway, E.G. Hope, A.K. Brisdon, H.W. Kroto and D.R.M. Walton,
    J. Chem. Soc., Perkin Trans., 1995, 181.
  2. Reactions of Transition-metal Carbonyls with Anhydrous HF.
    S.A. Brewer, J.H. Holloway and E.G. Hope,
    J. Fluorine Chem., 1995, 70, 167.
  3. Ruthenium and Osmium Acyl Fluoride Complexes. Crystal Structure of [OC-6-13][RuF2(CO)2(PPh3)2].CD2Cl2.
    S.A. Brewer, K.S. Coleman, J. Fawcett, J.H. Holloway , E.G. Hope, D.R. Russell and P.G. Watson,
    J. Chem. Soc., Dalton Trans., 1995, 1073.
  4. Cleavage of both Alkyl C-H bonds and Aryl C-F bonds and Concomitant C-C Bond Formation in a Pentamethylcyclopentadienylrhodium Phosphine Complex: X-Ray Structure of [{h 5-C5Me3[CH2C6 F4P(C6F5)CH2]2-1,3}RhCl]+BF4-.
    M.J. Atherton, J. Fawcett, J.H. Holloway, E.G. Hope, A. Karacar, D.R. Russell and G.C. Saunders,
    J. Chem. Soc., Chem. Commun., 1995, 191.
  5. Tris(2,6-Difluorophenyl)Phosphite Complexes of Platinum Group Metals: Structure of of trans-PtCl2(PEt3){P(O-2,6-C6H3F2)3}.
    K.S. Coleman, J.H. Holloway, E.G. Hope, D.R. Russell, G.C. Saunders and M.J. Atherton, Polyhedron, 1995, 2107.
  6. 177.Isolation of H2S....ClF in a Pre-reactive Mixture of H2S and ClF Expanded in a Coaxial Jet and Characterisation by Rotational Spectroscopy.
    H.I. Bloemink, K. Hinds, J.H. Holloway and A.C. Legon,
    Chem. Phys. Letters, 1995, 242, 113.
  7. The Complex OC.....ClF Identified as a Pre-chemical Intermediate by Rotational Spectroscopy of Carbon Monoxide-Chlorine Monofluoride Mixtures.
    K. Hinds, J.H. Holloway and A.C. Legon,
    Chem. Phys. Letters, 1995, 242, 407.
  8. Characterisation of a Pre-reactive Intermediate in Gas-phase Mixtures of Fluorine and Ammonia: the Rotational Spectrum of the H3N...F2 Complex.
    H.I. Bloemink, K. Hinds, J.H. Holloway and A. C. Legon,
    Chem.Phys. Letters, 1995, 245, 598.
  9. Synthesis and Characterisation of Iridium Carbonyl Fluorides.
    S.A. Brewer, A.K. Brisdon, J.H. Holloway, E.G. Hope, L.A. Peck and P.G. Watson,
    J.Chem.Soc., Dalton Trans, 1995, 2945.
  10. Reactions of cis-[Os(CO)4Me2] and cis-[Re(CO)4(PPh3)Me] with Anhydrous HF and HOTeF5. Compatability of Phosphine, Alkyl and OTeF5- Ligands in Low-valent Transition-Metal Complexes.
    S. A. Brewer, L.A. Buggey, J.H. Holloway and E.G. Hope,
    J.Chem.Soc., Dalton Trans, 1995, 2941.
  11. Pre-reactive Intermediates in Mixtures of Hydrocarbons with Chlorine Monofluoride: Characterisation of Ethyne.....ClF and Ethene....ClF by Rotational Spectroscopy.
    H.I. Bloemink, K. Hinds, A.C. Legon and J.H. Holloway,
    J.Chem.Soc., Chem. Commun., 1995, 1833.
  12. Pentafluorophenylphosphine Complexes of Rhodium (1): Extended X-Ray Absorption Fine Structure Studies of [{Rh[PPhx(C6F5)3-x]2(m -Cl)}n} (x = 0-2) and [{Rh[C6F5]2 PCH2CH2P (C6F5)2](m -Cl) }2]. Crystal Structures of [Rh Cl(PPh3){(C6F5)2 PCH2CH2P (C6F5)2}]C4H8O and (C6F5)2 PCH2CH2P (C6F5)2.
    M.J. Atherton, K.S. Coleman, J. Fawcett, J.H. Holloway, E.G. Hope, A. Karaçar, L.A. Peck and G.C. Saunders.
    J.Chem.Soc., Dalton Trans, 1995, 4029.
  13. EXAFS studies on Low-valent Transition Metal Fluorides.
    K.C. Coleman, J.H. Holloway, E.G. Hope, L.A.Peck and A.K. Brisdon.
    Synchroton Radiation Department Scientific Reports, 1994-95, II, 380, Ed. R.J. Cernik. Annual Report 1994-1995, Daresbury Laboratory.
  14. EXAFS Studies on Bromine Oxide Fluorides.
    J.H. Holloway , E.G. Hope, L. Wootton and A.K. Brisdon.
    Synchroton Radiation Department Scientific Reports, 1994-95, II, 388, Ed. R.J. Cernik. Annual Report 1994-1995, Daresbury Laboratory.
  15. Tris (Pentafluorophenyl) Phosphine Complexes of Iridium: Molecular Structure of IrBr(CO){ P(C6F5)3} 2.
    J.H. Holloway, E.G. Hope, D.R. Russell and G.C. Saunders,
    Polyhedron, 1996, 15, 173.
  16. Is the Gas-Phase Complex of Ammonia and Chlorine Monofluoride H3N...ClF or [H3NCl]+...F-? Evidence from Rotational Spectroscopy.
    H.I. Bloemink, C.M. Evans, J.H. Holloway and A. C. Legon,
    Chem.Phys. Letters, 1996, 248, 260.
  17. Selective Fluorination of Dichloromethane by Highest Oxidation State Transition-metal Oxide Fluorides.
    J.H. Holloway, E.G. Hope, P.J. Townsend and R.L. Powell
    J. Fluorine Chem., 1996, 76, 105.
  18. Novel Synthesis Using Inorganic Fluorides.
    J.H. Holloway and E.G. Hope.
    J. Fluorine Chem., 1996, 76, 209.
  19. The Oxidative Fluorination of the Platinum Metals by Elemental Fluorine in Solution at Room Temperature.
    J.H. Holloway, E.G. Hope and C.D. Puxley.
    Eur. J. Solid State Inorg. Chem., 1996, 33, 821.
  20. Carbon-Fluorine and -Hydrogen Bond Activation and Carbon-Carbon Bond Formation in h 5-Pentamethylcyclopentadienyl-rhodium and -iridium Phosphine Complexes; Crystal structures of [M(h 5 -C5Me5)Cl{(C6F5)2P CH2 CH2P(C6F5)2}]+BF4- (M=Rh or Ir).
    M.J. Atherton, J. Fawcett, J.H. Holloway, E.G. Hope, A. Karaçar, D.R. Russell and G. C. Saunders.
    J. Chem.Soc., Dalton Trans, 1996, 3215.
  21. Rotational Spectrum and Properties of a Complex of Hydrogen Cyanide and Chlorine Monofluoride.
    K. Hinds, A.C. Legon and J.H. Holloway.
    Mol.Phys., 1996, 88, 673.
  22. Geometry and Nature of the Binding of the Pre-reactive Complex C2H4...ClF from its Rotational Spectrum.
    H.I. Bloemink, J.H. Holloway and A. C. Legon.
    Chem.Phys.Letters, 1996, 250, 567.
  23. Are B...ClF Bonds Linear? The Angular Geometry of a Pre-reactive Complex of Oxirane and Chlorine Monofluoride from Rotational Spectroscopy.
    H.I. Bloemink, C.M. Evans, J.H. Holloway and A. C. Legon.
    Chem.Phys.Letters, 1996, 251, 275.
  24. Mulliken Inner Complexes [(CH3)3Cl]+...F- in Pre-reactive Mixtures of Trimethylamine and Chlorine Monofluoride: Identification and Characterisation by Rotational Spectroscopy.
    H.I. Bloemink, J.H. Holloway and A. C. Legon.
    Chem.Phys.Letters, 1996, 254, 59.
  25. Evidence for a Pre-reactive Intermediate in a Gaseous Mixture of Ethyne and Chlorine Monofluoride.
    K. Hinds, J.H. Holloway and A. C. Legon.
    J. Chem. Soc., Faraday Trans., 1996, 92, 1291.
  26. Nature and Angular Geometry of the Pre-reactive Complex Thiirane-Chlorine Monofluoride from its Rotational Spectrum.
    C.M. Evans, J.H. Holloway and A. C. Legon.
    Chem. Phys. Letters, 1996, 255, 119.
  27. Molecular Geometry of SO2 ... ClF from its Rotational Spectrum: A Cis, Planar Complex with a Linear O ... Cl-F bond.
    G. Cotti, J.H. Holloway and A.C. Legon.
    Chem. Phys. Letters, 1996, 255, 401.
  28. A Complex of Molecular Fluorine with an Organic Compound Detected in the Gas Phase: the Rotational Spectrum of CH3CN ... F2.
    G. Cotti, S.A. Cooke, C.M. Evans, J.H. Holloway and A. C. Legon.
    Chem. Phys. Letters, 1996, 260, 388.
  29. The Pre-reactive Complex H2O ... ClF Identified in Mixtures of Water Vapour and Chlorine Monofluoride by Rotational Spectroscopy.
    S.A. Cooke, G. Cotti, C.M. Evans, J.H. Holloway and A. C. Legon.
    J. Chem. Soc., Chem. Commun., 1996, 2327.
  30. Cis-Dichloro (triethylphosphine-P) [tris(2,6-difluorophenyl) phosphite-P] Platinum (II).
    J. Fawcett, J.H. Holloway, E.G. Hope, G.C. Saunders and M.J. Atherton.
    Acta Cryst., 1996, C52, 2463.
  31. Rotational Spectrum and Properties of a Gas-Phase Complex of Fluorine and Hydrogen Cyanide.
    S.A. Cooke, G. Cotti, C.M. Evans, J.H. Holloway and A. C. Legon.
    Chem. Phys. Letters, 1996, 262, 308.
  32. Rotational Spectroscopy of a Pre-reactive Mixture of H2S and F2: Detection and Characterisation of the Weakly Bound Complex H2S....F2.
    G. Cotti, C.M. Evans, J.H. Holloway and A. C. Legon.
    Chem. Phys. Letters, 1997, 264, 513.
  33. Pentafluorophenylphosphine Complexes of Rhodium (I)
    K.S. Coleman, J.H. Holloway, E.G. Hope, G.C. Saunders and M.J. Atherton
    Synchroton Radiation Department Scientific Reports, 1995-96, I, 83, Ed. R.J. Cernik and E. Towns-Andrews 1995-1996, Daresbury Laboratory.
  34. The Rotational Spectrum and Angular Geomettry of a Pre-reactive Complex of Allene and Chorine Monofluoride.
    S.A. Cooke, J.H. Holloway and A.C. Legon.
    Chem. Phys. Letters, 1997, 266, 61.
  35. Rotational Spectrum and Angular Geometry of a Pre-reactive Complex of Oxirane and F2.
    C.M. Evans, J.H. Holloway and A.C. Legon.
    Chem. Phys. Letters, 1997, 267, 281.
  36. Detection and Characterisation of a Pre-reactive Complex of a Mixture of Water and Fluorine: Rotational Spectrum of H2O....F2.
    S.A. Cooke, G. Cotti, J.H. Holloway and A.C. Legon.
    Angew. Chem. Int. Ed. Engl., 1997, 36, 129.
  37. Preparation and Characterisation of Dimolybdenum Complexes Containing Fluorophenylimide Ligands.
    P. Bhattacharyya, J. Fawcett, J.H. Holloway, E.G. Hope and G.C. Saunders.
    J.Chem.Soc., Dalton Trans., 1997, 199.
  38. Structural and Electronic Impact of Fluorine in the Ortho Positions of the Phenoxy Groups of Phenyl-Phosphonite and -Phosphinite Ligands in Compounds of Platinum-Group Metals.
    M.J. Atherton, J. Fawcett, A.P. Hill, J.H. Holloway, E.G. Hope, D.R. Russell, G.C. Saunders and R.M.J. Stead.
    J.Chem.Soc., Dalton Trans., 1997, 1137.
  39. Synthesis and Characterisation of Ruthenium Carbonyl Fluorides
    K.S. Coleman, J.H. Holloway and E.G. Hope.
    J. Chem. Soc., Dalton Trans., 1997, 1713.
  40. Halogen and Interhalogen Reactions with [60] Fullerene: Preparation and Characterization of C60Cl24 and C60Cl18F14.
    A.J. Adamson, J.H. Holloway, E.G. Hope and R. Taylor.
    Fullerene Sci. and Tech., 1997, 5, 629.
  41. Pentaflurophenylphosphine Complexes of Platinum (II); Crystal Structure of trans-[PtCl2(PEt3){PPh2(C6F5)}]
    M.J. Atherton, J. Fawcett, J.H. Holloway , E.G. Hope, D. R. Russell and G.C. Saunders.
    J. Chem. Soc., Dalton Trans., 1997, 2217.
  42. Air-stable Ruthenium (II) and Osmium (II) Fluoride Complexes. Crystal Structures of [OC-6-13][MF2(CO)2(PR3)2][M=Ru, PR3=PEtPh2; M=Os, PR3=PPh3 or P(C6H11)3].
    K.S. Coleman, J. Fawcett, J.H. Holloway, E.G. Hope and D. R. Russell.
    J. Chem. Soc., Dalton Trans, 1997, 3557.
  43. Reaction of Ruthenium (II) and Osmium (II) Hydrides with Anhydrous HF
    K.S. Coleman, J.H. Holloway, E.G. Hope and J. Langer.
    J. Chem. Soc., Dalton Trans, 1997, 4555.
  44. Configuration at Oxygen and Deviation of the O...Cl-F System from linearity in 2,5-Dihydrofuran...ClF from Rotational Spectroscopy.
    S.A. Cooke, G.K. Corlett, C.M. Evans, J.H. Holloway and A.C. Legon.
    Chem. Phys. Letters, 1997, 275, 269.
  45. A pseudo-p Analogue of a Mulliken bp.as Type Complex: The Rotational Spectrum of Cyclopropane-Chlorine Monofluoride.
    K. Hinds, J.H. Holloway and A.C. Legon.
    J.Chem.Soc., Faraday Trans., 1997, 93, 373.
  46. Identification and Characterization of a Gas-Phase Complex of Methylenecyclopropane and Chlorine Monofluoride by Rotational Spectroscopy.
    S.M. Cooke, J.H. Holloway and A.C. Legon.
    J.Chem. Soc., Faraday Trans., 1997, 93, 4253.
  47. Identification and Geometry of the Pre-reactive Complex Buta-1,3-diene ....ClF by Rotational Spectroscopy.
    S.A. Cooke, J.H. Holloway and A.C. Legon.
    J. Chem. Soc., Faraday Trans., 1997, 93, 2361.
  48. Solution Decomposition of Platinum (II) Fluoride Cations; Single-Crystal Structure of [Pt(PPh3)2 (C6H4PPh2][SbF6] CD2Cl2.
    H. C. S Clark, J. Fawcett, J.H. Holloway , E.G. Hope, L.A. Peck and D. R. Russell.
    J.Chem Soc., Dalton Trans., 1998, 1249.
  49. Mild Fluorination of Oxo-anions; a Clean Route to Group 6 and 7 Transition Metal Oxide Fluorides.
    A.K. Brisdon, J.H. Holloway and E.G. Hope.
    J. Fluorine Chem., 1998, 89, 35.
  50. Carbon-Fluorine Bond Activation in the Reactions between 1, 2-bis[bis-(2,6-difluorophenyl) phosphino] ethane and [{MCl(m-Cl)h 5-C5Me5)} 2](M=Rh or Ir).
    J. Fawcett, S. Friedrichs, J.H. Holloway, E.G. Hope, V. McKee, M. Nieuwenhuyzen, D. R. Russell and G.C. Saunders.
    J.Chem Soc., Dalton Trans, 1998, 1477.
  51. Activation of C-F and C-H Bonds by Polyalkylcyclopentadienylrhodium Complexes: Crystal Structure of [(h 5-C5Me4Et)RhCl{ (C6F5)2 PCH2CH2P (C6F5)2} ]+BF4-.
    M.J. Atherton, J. Fawcett, J.H. Holloway, E.G. Hope, S.M. Martin, D.R. Russelland G.C. Saunders.
    J. Organomet. Chem., 1998, 555, 67.
  52. Self-Assembly of a Chiral-at-Metal Rhodium Complex Cation via Regioselective Carbon-Fluorine and -Hydrogen Bond Activation and Carbon-Carbon Formation.
    M. Atherton, J.H. Holloway, E.G. Hope and G. C Saunders.
    J. Organomet. Chem., 1998, 558, 209.
  53. Interaction of Benzene and Halogens in the Gas-phase; Rotational Spectrum of C6H6....ClF
    S.A. Cooke, C.M. Evans, J.H. Holloway and A.C. Legon.
    J.Chem Soc., Faraday Trans., 1998, 94, 2295.
  54. Isolation of Oxides and Hydroxides Derived from Fluoro(60)fullerenes.
    O. Boltalina, J.H. Holloway, E.G. Hope, J.M. Street and R. Taylor.
    J. Chem. Soc., Perkin Trans.2, 1998, 1845.
  55. Angular Geometries of Complexes Containing the O....Cl-F Linkage: Rotational Spectrum of Formaldehyde....Chlorine Monofluoride.
    S.A. Cooke, G.K. Corlett, C.M. Evans, A.C. Legon and J.H. Holloway.
    J. Chem. Phys., 1998, 108, 39.
  56. Evidence Concerning the Relative Nucleophilicities of Non-bonding and p -Bonding Electrons in Furan from the Rotational Spectrum of Furan ....ClF.
    S.A. Cooke, G.K. Corlett, J.H. Holloway and A.C. Legon.
    J. Chem. Soc., Faraday Trans., 1998, 94, 2675.
  57. Reactions of Iridium and Rhodium Hydrides with Anhydrous HF; Crystal Structure of [Rh(CO)(PPh3)3][BF4].thf.
    H.C.S. Clark, K.S. Coleman, J. Fawcett, J.H. Holloway, E.G. Hope, J. Langer and I.M. Smith.
    J. Fluorine Chem., 1998, 91, 207.

index 1960-64 1965-69 1970-74 1975-79 1980-84" 1985-89 1990-94 1995-99


Last updated: 10 August 1999 12:05
Dr E.G. Hope

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